Tetsurou Kuroo, Morisuke Yaku, Kenma Kozume

Kuroo Tetsurou: He has a laid-back but still intriguing personality and is considered an "expert in provocation." He is commonly seen smiling when things go his way. He is quite kind and is willing to help others improve. During matches, he tends to be a cautious person, true to Nekoma's style. He generally implements the strategies designed by Kenma, demonstrating his blind faith in him.

Kenma Kozume: Kenma usually has a calm, serene, and analytical personality. He rarely loses his temper and generally does not get too excited or enthusiastic about most things. He does not like to stand out or be noticed in any way, nor does he like the authority that comes with being a senior student.

Yaku Morisuke: Yaku is quite an honest, straightforward, and hardworking person who has a lot of confidence in his abilities as a libero and takes care of his team, especially the first-year students. He can also be incredibly irascible, especially regarding Lev, who seems to find Yaku's fits of rage "terrifying," although these outbursts are typically in response to Lev's tactless comments about Yaku's height and/or his attempts to skip receiving practice with him. Even Kuroo sometimes refers to him as a "demon senpai." Yaku takes pride in playing as a libero and especially considers it a great honor to play libero for Nekoma.